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A novel chemical pathway for energy efficient

The efficient removal of calcium and magnesium impurities from titanium slag to prepare a boiling chlorinated charge is one of the technical bottlenecks in producing high-end titanium products from titanium resources in Panxi. This work proposes a novel process to prepare boiling chlorinated charges from the modified titanium slag, which ...

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Titanium Extraction from Titania-Bearing Blast Furnace Slag: …

Low cost and green recycling of titania-bearing slag is an important aspect of the circular economy to ensure the sustainable development of the titanium industry. In this paper, the existing titanium extracting techniques are comprehensively summarized. The principles, advantages, as well as existing problems are clarified in relation to traditional …

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A detailed assessment of global Zr and Ti production

Sulfate ilmenite is best suited for titanium slag production (both chloride and sulfate slag), as high FeO is best for pig iron formation (which is important, as pig iron can be tapped off separately in the slag furnace to leave the Ti slag) (Plester pers. commun. 2018). There can be elements in the ilmenite that carry across and make the slag ...

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Chemistry and Mineralogy of Titanium-rich Slags

Titania slag represents an important feedstock for the manufacture of titanium dioxide pigment by the sulphate process. Moreover, part of the pro-duction of the titania-rich slag is further acid-leached under a high-pressure and moderate-temperature hydrometallurgical process to yield an upgraded titania slag with 94.5 mass percent TiO 2, which

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Life cycle assessment comparison of emerging and traditional Titanium …

A simplified flow sheet for the new ARTS process is shown in Fig. 1. Titanium slag is roasted with NaOH and washed to remove soluble impurities. The products of roasting and washing are dissolved in HCl acid, mixed with an amine extractant and phase-separated to preferentially extract iron, resulting in a virtually iron-free titanium …

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Titanium production by magnesium thermal reduction in …

The largest amount of titanium is present in slag samples from the surface of titanium electrode (from ∑ 3 wt% to ∑ 9 wt%). Therefore, the electrode mass loss in this experiment No. 5. is ...

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Titanium Slag Project Update

The titanium slag project started in early 2013. Construction was completed in mid-2014 and started to operate in September of the same year. Until March 2015 over 20,000 tonnes of qualified titanium slag has been produced, as well as 14,000 tonnes of reduced ilmenite. Henan Billions has received a positive response from users of both titanium ...

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Physicochemical properties and structure of titania …

The titanium industry can hardly bypass the titania-containing slags, and the slag physicochemical properties are essential in the metallurgical reactor design and process control. The TiO2–FeO-based slags and TiO2–SiO2–CaO-based slags are the main metallurgical slag systems in the titanium resource utilization processes. To elaborate …

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China tio2 slag imports and tio2 exports analysis in the first …

In particular, the competition for raw materials such as high-quality high-titanium slag and artificial rutile suitable for the production of titanium dioxide by the chloride process will further intensify. Data analysis of titanium dioxide; According to customs statistics, China imported 13,900 tons of titanium dioxide in June, a year-on …

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Evaluation of Titania-Rich Slag Produced from Titaniferous

Titanium-bearing magnetite ore is generically defined as magnetite with > 1% titanium dioxide (TiO2) and is usually vanadium-bearing. The iron and titanium occur as a mixture of magnetite (Fe3O4) and ilmenite (FeTiO3) with vanadium oxide usually occurring within the solid solution of the titanium-bearing magnetite phase. These ores are …

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Production of Rutile TiO2 Pigment from Titanium Slag …

An alternative route was proposed for preparing rutile titanium dioxide (TiO2) white pigment. The process involves the digestion of titanium slag with sulfuric acid, subsequent hydrolysis of unenriched titanyl sulfate solution with ammonia, low-temperature calcination, and unseeded crystallization, producing a high-quality rutile TiO2 white pigment. The …

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Synthesis and Characterization of Titanium Slag from …

Titanium rich slag has emerged as a raw material for alternative titanium source. Ilmenite contains 42–50% TiO2 as the mineralogical composition depending on the geographical resources. Application of titanium in paper, plastic, pigment and other various industries is increasing day by day. Due to the scarcity of natural raw mineral rutile …

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Influence of TiO2, Al2O3, and Basicity on Viscosity and …

High titanium-bearing blast furnace slag is the main type of blast furnace slag produced by vanadium and titanium ore in the Panzhihua area during blast furnace smelting, which is mainly composed of oxides such as CaO, SiO 2, MgO, Al 2 O 3, and TiO 2, and when the temperature is constant, the viscosity of the slag mainly depends on …

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Purification of titanium oxycarbonitride by leaching from titanium slag …

The high titanium slag was supplied by Liaoning Guorun Group Co., Ltd., China. 2.2. Carbothermal reduction of high titanium slag. Before carbothermal reduction, the high titanium slag was mixed with graphite based on the stoichiometric amount of the possible carbothermal reduction reactions. This mixture was homogenized by ball milling …

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Titanium: An Overview of Resources and Production Methods …

Processes for the manufacture of titanium powder directly as extractive metallurgical products include the manufacture of Ti from TiCl 4, purified TiO 2, and/or improved titanium slag (UGS) with a TiO 2 content greater than 90%. Upgraded titanium slag (UGS) is one of the fundamental products of the carbothermal reduction of titanium …

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Physicochemical properties and structure of titania …

The titanium industry can hardly bypass the titania-containing slags, and the slag physicochemical properties are essential in the metallurgical reactor design and …

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High-Titanium Slag Preparation Process by …

Titanium slag can be classified as ultra-grade slag (UGS) and high-grade slag (HGS). UGS is preferred for producing titanium dioxide via chlorination, while HGS, …

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Behavior of vanadium during reduction and smelting of …

At last, the vanadium-bearing pig iron and titanium slag were separated and crushed for subsequent analysis. 2.2 Definition of parameters (1) Vanadium distribution ratio (LV) The vanadium distribution ratio between the titanium slag and the molten iron is expressed as sV m (V) (V) c L c  (1) where cs(V) and cm(V) represent the contents ...

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The effect of B2O3 on the structure and properties of titanium slag

Synthetic rutile was prepared from titanium slag melt with a low amount of additive (B 2 O 3) and low energy consumption in our previous work.The mechanism by which B 2 O 3 promotes the precipitation of the rutile phase during the cooling and crystallization of titanium slag melt is not clear and needs further theoretical study. The …

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Effect of mineral phases on the leaching efficiency of Ti slag

Titanium slag obtained from electric-furnace smelting using ilmenite from Panzhihua contains predominately two phases: anosovite and augite. The mineral phase compositions in titanium slag can have severe effects on the leaching process and leaching efficiency.

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Minerals, slags, and other feedstock for the …

Titanium dioxide slags are produced by reduction smelting of ilmenite in electric arc furnaces. The slag grade (sulfate or chloride) depends essentially on the …

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AN OVERVIEW OF SOUTH AFRICA'S TITANIUM …

Richards Bay Minerals (RBM) is the largest titanium slag producer in the world with annual productions of about 1 Mt, and mining reserves estimated to last around 20 years at current production rates. Namakwa Sands, formerly owned by Anglo American Operations but acquired by Exxaro in 2007, is another major player in the production of titanium ...

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Evaluation of Titania-Rich Slag Produced from …

Fluxless smelting in a direct-current open-arc furnace is proposed as an opportunity to improve iron and vanadium recovery and potentially unlock the titanium as …

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DUBAL's titanium project in Oman is expected to start

"With the laying of the foundation stone for a titanium slag facility in the Sohar Free Zone in the Sultanate of Oman, the Sohar Titanium Project, a strategic project with DUBAL Holding as one of the shareholders, made good progress during the year. ... will produce 150,000 tonnes per year of titanium dioxide. It said the project is a strategic ...

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Titanium production worldwide by country 2022 | Statista

The total global mine production of titanium minerals amounted to an estimated 9.5 million metric tons in 2022. Ilmenite accounted for over 90 percent of the overall titanium production from mines ...

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Structural role of titanium on slag properties

The presence of titanium in ground granulated blast-furnace slags (GGBS) has been suspected to modify cement properties. This study provides the first evidence of a relation between the TiO 2 content of slags and the mechanical properties of mortars based on slag cements. It is observed that only the slags containing less than 1%TiO 2 show a …

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Recovery of Vanadium, Titanium, and Iron from Vanadium

Additionally, a qualified high-titanium slag product has been obtained. Compared with the traditional method, (NH 4) 2 SO 4 low-temperature cascade roasting method has the advantages of low energy consumption and high extraction rate of valuable metals. Thus, the significance of carrying out this work could provide scientific reference …

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Titania-Slag

Titanium slag is produced in the mining, refining and smelting of mineral sands to produce titanium dioxide (TiO2) feedstocks used in the production of pigments, titanium metal, welding fluxes and other specialised products. High-titania slag was prepared in a pilot-scale DC furnace from ilmenite concentrates with different levels of uranium ...

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A literature review of titanium metallurgical processes

Research highlights Various titanium metallurgical processes for the production of titanium dioxide and titanium metal have been reviewed and compared including: Processes to upgrade ilmenite to synthetic rutile. Thermo-chemical Kroll and Hunter processes. Electro-chemical processes for direct reduction of TiO 2 and electro …

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A literature review of titanium metallurgical processes

Approximately 95–98% Ti in the titanium slag could be extracted under optimal conditions. In addition, the TiO 2 purity in the product was up to 99.3%. A similar process …

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